Oil-oil and oil-source rock correlations in the Alpine Foreland Basin of Austria: Insights from biomarker and stable carbon isotope studies     

Reinhard Gratzer  Achim BechtelReinhard F. Sachsenhofer  Hans-Gert LinzerDoris Reischenbacher  Hans-Martin Schulz 《Marine and Petroleum Geology》2011,28(6):1171-1186

The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schöneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of different fields are only in the western part consistent with northward displacement of immature oils by subsequently generated oils. In the eastern part of the basin different migration pathways must be assumed. The trend in S/(S + R) isomerisation of ααα-C₂₉ steranes versus the αββ (20R)/ααα (20R) C₂₉ steranes ratio from oil samples can be explained by differences in thermal maturation without involving long-distance migration. The results argue for hydrocarbon migration through highly permeable carrier beds or open faults rather than relatively short migration distances from the source. The lateral distance of oil fields to the position of mature source rocks beneath the Alpine nappes in the south suggests minimum migration distances between less than 20 km and more than 50 km.Biomarker compositions of the oils suggest Oligocene shaly to marly successions (i.e. Schoeneck, Dynow, and Eggerding formations) as potential source rocks, taking into account their immature character. Best matches are obtained between the oils and units a/b (marly shale) and c (black shale) of the “normal” Schöneck Formation, as well as with the so-called “Oberhofen Facies”. Results from open system pyrolysis-gas chromatography of potential source rocks indicate slightly higher sulphur content of the resulting pyrolysate from unit b. The enhanced dibenzothiophene/phenanthrene ratios of oils from the western part of the basin would be consistent with a higher contribution of unit b to hydrocarbon expulsion in this area. Differences in the relative contribution of sedimentary units to oil generation are inherited from thickness variations of respective units in the overthrusted sediments. The observed trend towards lighter δ¹³C values of hydrocarbon fractions from oil fields in a W-E direction are consistent with lower δ¹³C values of organic matter in unit c.  相似文献   

E5000型全谱直读型电弧发射光谱仪研制及其在地球化学样品分析中应用   总被引：2，自引：2，他引：0  

俞晓峰  李锐  寿淼钧  郑存江  胡勇平 《岩矿测试》2015,34(1):40-47

在地球化学样品检测工作中,Ag、B、Sn等难分析元素通常采用传统的交流电弧发射光谱法(摄谱仪),随着地球化学样品数量的增加以及对检测结果质量要求的提高,该方法操作复杂、分析过程繁琐的问题与日常大量样品分析的矛盾日益突出,多道式电弧直读发射光谱也开始在行业内应用。本文基于先进的数字光源技术和CCD全谱型光谱仪技术,改进了电弧发生系统、分光系统和检测系统,将电弧激发光源与Paschen-Runge型全谱CCD光谱仪结合,研制了一款新型的台式全谱直读型电弧发射光谱仪E5000。E5000型电弧发射光谱仪通过激光定位结合程控电极技术,自动调整电极位置,提高了采谱过程的精度控制;利用CCD全谱技术获得了激发样品的全谱信息,可轻易实现光谱信号的背景扣除和干扰校正;且无需再次测定黑度,直接获得分析结果;同时结合内标法和标准加入法,可以进一步提高复杂基体样品的分析精准度。应用研制的光谱仪对水系沉积物和土壤样品进行检测,Ag、B、Sn元素的检出限分别达到了0.01μg/g、0.65μg/g、0.16μg/g,在分析水系沉积物、土壤时检测精密度基本小于10%,优于当前的摄谱法和多道电弧直读光谱法,满足了地球化学样品检测质量要求。  相似文献   

羌塘盆地羌资5井二叠系展金组烃源岩基本特征   总被引：2，自引：1，他引：1  

曹竣锋  宋春彦  付修根  陈明  郑博  孙伟 《海相油气地质》2015,(2)

前人对羌塘盆地的烃源岩研究资料主要来源于中生界地表露头,少见古生界的。对羌资5井二叠系展金组烃源岩的钻井岩心研究表明,其有机碳含量高,平均值达到1.15%,属于好烃源岩。干酪根显微组分主要为Ⅲ型,其次为Ⅱ2型;有机质主要来自于海相低等水生生物,热演化已达到成熟阶段。烃源岩具较好的生气能力。认为井下烃源岩样品虽显示其处于有机质演化成熟阶段,但因受后期构造抬升的影响,推测二叠系深部未知的烃源岩可能尚处于高成熟—过成熟阶段。羌塘盆地二叠系具有较好的勘探前景,油气勘探可向深部古生界开展。  相似文献   

巢湖地区二叠系栖霞组和三叠系南陵湖组石灰岩生物标志物特征与生烃潜力——以平顶山和马家山剖面为例     

宋换新  志刚  包建平 《海相油气地质》2015,(2)

对安徽巢湖地区平顶山和马家山剖面下二叠统栖霞组和下三叠统南陵湖组进行了地层沉积特征及暗色石灰岩生烃潜力的综合分析,并对这两个层位的样品进行了饱和烃生物标志物特征研究。结果表明,两个层位的石灰岩都属于有效烃源岩,均具有一定的生烃潜力。南陵湖组石灰岩饱和烃以高丰度的长链三环萜烷、重排藿烷、重排甾烷为特征,表明其形成于偏弱氧化的沉积环境。栖霞组沉积期水体能量相对较低,受陆源物质影响明显,栖霞组石灰岩萜烷系列为常规的分布模式,但其甾烷成熟度参数明显低于平衡值,认为高的热演化程度是造成栖霞组石灰岩20S/(20S+20R)-ααα-C29甾烷值和ββ/(ββ+αα)-C29甾烷值"倒转"的主要原因。  相似文献   

长白山区二道白河流域早更新世玄武质熔岩的成因   总被引：2，自引：1，他引：1  

马晗瑞  杨清福  盘晓东  武成智  陈聪 《岩石学报》2015,31(11):3484-3494

采用岩石化学和同位素分析方法,研究了二道白河流域早更新世玄武质熔岩的成因。玄武质熔岩由钠质拉斑玄武岩和钾质粗面玄武岩、玄武质粗面安山岩组成。它们的REE分配形式比较相近,表明它们来自共同的源区。Sr、Nd、Pb同位素示踪表明,二道白河流域早更新世玄武质熔岩岩浆源区接近于似原始地幔。它们的Mg#=100Mg O/(Mg O+Fe O)低于中国东部新生代玄武岩原始岩浆的Mg#(60~68),Ni(27.76×10-6~200.6×10-6)低于原始地幔,Rb/Sr(0.05~0.09)、Ba/Rb(15.64~264)高于原始地幔,说明这些岩石不是源自原始地幔。玄武质熔岩的DI变化于42~67,具有高Ca、高Sr、Eu正异常,微量元素图解显示玄武岩保留部分熔融趋势,粗面玄武岩、玄武质粗安岩具有结晶分异趋势,岩浆上升过程中发生了不同程度的地壳混染作用。玄武质熔岩的Nb/Ta之比为14.8~15.8,与勘察加半岛深俯冲带火山类似。Nb/Ta-(Na2O-K2O)关系图解显示研究区玄武质岩浆的形成与俯冲板片的部分熔融有关。  相似文献   

Characteristics and origin of carbon isotopes of n-alkanes in crude oils from the western Pearl River Mouth Basin,South China sea     

《Marine and Petroleum Geology》2015

The quantitative characterization of carbon isotopes of n-alkanes is commonly carried out in organic geochemical studies. Possible controls on carbon isotopes include source organic matter, maturity, fractionation during oil expulsion and migration, and the mixing of different oils. In this study of the origin of crude oils in the western Pearl River Mouth Basin, the influences of all of these factors have been considered in reaching a conclusion. Carbon isotopes of n-alkanes in the crude oils, and the extracts of the two effective source rocks (the Wenchang and Enping formations) in the basin, exhibit clear differences. The Wenchang source rocks have heavy δ¹³C values that remain almost constant or become slightly heavier with increasing carbon number. The Enping source rocks have light δ¹³C values that become lighter with increasing carbon number. Two groups of oils in this area were identified based on the carbon isotopes of the n-alkanes; groupIoils are similar to extracts of the Wenchang source rocks. However, the groupIIoils are different from both the Wenchang and Enping source rocks and the carbon isotopic profiles of their n-alkanes exhibit a “V” feature with increasing carbon number. The results of artificial thermal maturation experiments indicate that, from the early stage to the peak stage of oil generation (with EasyRo between 0.64% and 1.02%), the δ¹³C values of n-alkanes in the pyrolysis oils become heavier by about 3‰ with increasing thermal maturity, but the shape of the carbon isotopic profiles are not significantly changed. Calculated δ¹³C values of n-alkanes in “mixed” artificial pyrolysis oils indicate that the mixture of oils generated from the same source rocks with different maturities could not change the carbon isotopic profile of the n-alkanes, however, a mixing of the Wenchang and Enping oils could give the “V” feature in the profiles, similar to the groupIIoils in this area. The groupIIoils appear to be mixed Wenchang and Enping oils, the latter being the dominant component in the mixture. We conclude that the source organic matter and the degree of mixing are the main factors controlling the carbon isotopic characteristics of n-alkanes in crude oils in the western Pearl River Mouth Basin.  相似文献   

高精度差分GPS/INS组合系统中的模糊度处理策略     

杨剑  王泽民  吴浩  戴富军 《测绘科学》2011,36(6):138-140

本文简要介绍了差分GPS/INS组合系统在单历元模式和多历元模式下适用的模糊度基本解算方法,分析了各自的优缺点,并提出了一种综合的GPS/INS组合系统模糊度处理策略。实验表明,在综合两种模式的动态模糊度解算方法的基础上引入基于周跳探测修复的模糊度传递以及INS辅助,对于不良观测条件下的模糊度固定具有十分显著的改善。  相似文献   

超低仰角扫描改进高山雷达降水估测   总被引：3，自引：1，他引：2       下载免费PDF全文

徐八林  刘黎平  王改利 《高原气象》2011,30(5):1337-1345

利用2004年5月云南大暴雨过程的26次昆明雷达超低仰角对比观测体扫资料,分析了昆明雷达0°和0.5°仰角数据以及对比了定量估测降水的情况。结果表明：0°仰角探测到的降水分布范围更大;与0.5°仰角相比,通过定量计算,探测降水范围能提高约9.96%,估测的降水总量约为11.6%。从探测到的降水量和范围来看,0°仰角较0...  相似文献   

考虑震源破裂过程的青海玉树地震震动图研究   总被引：4，自引：0，他引：4  

陈鲲  俞言祥  高孟潭  吕红山 《中国地震》2011,27(1):56-64

为了在缺少实时台站数据的情况下,研究震后地表地震动分布,本文尝试通过对震源做出某些约束,以提高震动图的精度.由于青海玉树地震的发震断层近似直立(倾向83°),震源破裂过程在时间和空间上呈明显的分区特征,分别考虑了地表破裂的线源发生模型和主震震级分解方法,用考虑了场地效应的震动图快速生成方法生成震动图.将两种方法生成的震动图与调查烈度比较.结果表明,基于震源破裂过程对主震震级进行分解,综合考虑各子事件生成震动图的方法,对震后的应急决策和灾情的快速评估是可行的.  相似文献   

龙潭水库诱发地震震源参数分析     

乔慧珍  张永久  任月霞  宫悦  赵敏 《四川地震》2011,(4):16-20

利用广西龙滩水库地震台网记录的数字地震波资料,用波谱分析方法计算了龙滩水库库区ML2．5—4．5级共计95个地震的震源参数。并对震源参数进行分析,结果表明：库区视应力的范围在0-3．5巴之间,2007年7月17日库区最大4．5级地震的视应力最大,为3．07巴。视应力随震级的增大呈幂函数增大趋势,两者的拟合关系为：σap...  相似文献